Tetrahedron Letters p. 5671 - 5672 (1988)
Update date:2022-08-05
Topics:
Yamaguchi, Masao
Takata, Toshikazu
Endo, Takeshi
While 1-oxo-4-methoxy-2,2,6,6-tetramethylpiperidinium chloride 1 does not oxidize the hydroxy group of 2-hydroxyethyl benzoate and 3-hydroxypropyl benzoate, it oxidizes those of 4-hydroxybutyl benzoate, 5-hydroxypentyl benzoate and 6-hydroxyhexyl benzoate.Oxidation of 2-hydroxyethyl 4-hydroxybutyl phthalate with 1 selectively gives 2-hydroxyethyl 4-oxobutyl phthalate.
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