Synlett p. 367 - 370 (1997)
Update date:2022-08-02
Topics:
Faraldos, Juan
Arroyo, Elisa
Herradón, Bernardo
A new catalytic activity of the enzyme acylase I (AA-I) from Aspergillus species has been found. Although this enzyme had previously been used only in the hydrolysis of N-acylamino acids, we have found that it is a highly efficient catalyst for transesterifications using vinyl esters as acyl donors. The method has been applied to the kinetic resolution of a variety of secondary alcohols.
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