Generation and reactivity of unsaturated iridium and rhodium dimethyl complexes

DOI: 10.1021/om00158a024

Source and publish data:

Organometallics p. 2254 - 2261 (1990)

Update date:2022-08-05

Topics: Reactivity Experimental Generation Unsaturated Rhodium Iridium

Authors:

Lundquist, Eric G.

Folting, Kirsten

Huffman, John C.

Caulton, Kenneth G.

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Protonation (HBF₄·OEt₂) of MMe₃P₃ (M = Rh, Ir; P = PMe₂Ph) in CH₂Cl₂ gives CH₄ and cis,mer-MMe₂P₃BF₄, characterized as a fluxional (me

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