Functional Group Manipulation along the Perimeter of a Hemispherical Molecule. Synthesis of Dihydro- and Tetrahydro-C16-hexaquinacene

DOI: 10.1021/jo00282a018

Source and publish data:

Journal of Organic Chemistry p. 5039 - 5043 (1989)

Update date:2022-08-05

Topics:

Authors:

Paquette, Leo A.

Galatsis, Paul

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00282a018

The synthesis of tetrahydro-C16-hexaquinacene (2) was successfully achieved by reduction of enedione 4 to 5a and subsequent exposure of this enediol to diphenyl disulfide and tri-n-butylphosphine in refluxing tetrahydrofuran.The resulting bis(phenylthio)

Full text of DOI:10.1021/jo00282a018

Products guided by the article

Product name:exo-9-(phenylthio)-2,2a,3,4,4a,4b,5,7a,7b,7c-decahydro-3,4,5-<1>-propanyl<3>ylidene-1H-dicyclopentapentalen-1-endo-ol

Cas No:123152-24-9

R&D Labs maybe for 123152-24-9

Hangzhou Donglou Bio-nutrient Co., Ltd.

Contact:+86-571-82225795,13967112289

Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang
Ningbo J&S Botanics Inc.

Contact:86-574-26865651

Address:529 YuanBaoShan Road, Beilun District
Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Jiangsu Dacheng Pharmaceutical and Chemical Co.,Ltd

Contact:+86-0517-87036900

Address:Chuzhou Chemical park, Huai'an, Jiangsu Province
Zhejiang Sanmei Chemical Industry Co., Ltd

Contact:86-579-87633213

Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.

Relevant to this article

Rational targeting of active-site tyrosine residues using sulfonyl fluoride probes

Doi:10.1021/cb5009475
(2015)
Pentacoordinate silicon intermediates in relay substitution reactions of organosilanes: successive nucleophilic attack at silicon and its adjacent carbon

Doi:10.1016/0022-328X(88)87105-5
(1988)
Synthesis of novel 1,2,3,4-tetrahydrocarbazole derivatives of biological interest

Doi:10.1080/10426500902839863
(2010)
Synthesis, structural characterization and growth features of some (Ph)Se-Cd cluster compounds (Ph = phenyl)

Doi:10.1016/j.poly.2010.02.023
(2010)
Neuroprotective and Antineuroinflammatory Effects of Hydroxyl-Functionalized Stilbenes and 2-Arylbenzo[b]furans

Doi:10.1021/acs.jmedchem.7b00376
(2017)
C-H bond activation and subsequent C(sp²)-C(sp³) bond formation: Coupling of bromomethyl and triphenylphosphine in an iridium complex

Doi:10.1021/om100187t
(2010)

Article Doi