Functional Group Manipulation along the Perimeter of a Hemispherical Molecule. Synthesis of Dihydro- and Tetrahydro-C16-hexaquinacene

DOI: 10.1021/jo00282a018

Source and publish data:

Journal of Organic Chemistry p. 5039 - 5043 (1989)

Update date:2022-08-05

Topics:

Authors:

Paquette, Leo A.

Galatsis, Paul

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Article abstract of DOI:10.1021/jo00282a018

The synthesis of tetrahydro-C16-hexaquinacene (2) was successfully achieved by reduction of enedione 4 to 5a and subsequent exposure of this enediol to diphenyl disulfide and tri-n-butylphosphine in refluxing tetrahydrofuran.The resulting bis(phenylthio)

Full text of DOI:10.1021/jo00282a018

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