Helvetica Chimica Acta p. 278 - 286 (1989)
Update date:2022-08-04
Topics:
Auberson, Yves
Vogel, Pierre
(1S,4R,5S,6S)-5-exo,6-exo-(Isopropylidenedioxy)-7-oxabicyclo<2.2.1>heptan-2-one ((-)-1) was transformed with high stereoselectivity to L-allose.Similarly, enantiomer (+)-1 was transformed into L-talose.The ketones (+)-1 and (-)-1 were derived from furan and 1-cyanovinyl (1S)-camphanate and 1-cyanovinyl (1R)-camphanate, respectively.
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(1994)
