SN2 ADDITIONS OF CUPRATES TO SULFONE AND ESTER-POLARIZED CYCLOPENTENYLIC SYSTEMS

DOI: 10.1016/0040-4020(89)80074-2

Source and publish data:

Tetrahedron p. 467 - 478 (1989)

Update date:2022-08-03

Topics:

Authors:

Pan, Y. Pan, Y.

Hutchinson, D. K.

Nantz, M. H.

Fuchs, P. L.

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Article abstract of DOI:10.1016/0040-4020(89)80074-2

The stereochemistry of SN2' addition of cuprates to sulfone and ester-polarized cyclopentenyl systems is shown to depend upon the nature of the leaving group.Allyl ammonium salts usually undergo stereospecific synfacial addition reactions.

Full text of DOI:10.1016/0040-4020(89)80074-2

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