
Tetrahedron Letters p. 1015 - 1018 (1996)
Update date:2022-08-04
Topics:
Delpech, Bernard
Calvo, Daniel
Lett, Robert
A new total synthesis of forskolin 1 has been achieved and this note describes the synthesis of the transfused enone 18 as a key-intermediate. Key steps are: 1) the intramolecular Diels-Alder reaction of 17 to afford the tricyclic lactone 8 (48-56%); 2) a
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