Synthesis of C19-C27 Fragment of Ansa Chain Part of Rifamycin S

DOI: 10.1246/cl.1989.117

Source and publish data:

Chemistry Letters p. 117 - 118 (1989)

Update date:2022-09-26

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Authors:

Katsuki, Tsutomu

Hanamoto, Takeshi

Yamaguchi, Masaru

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Article abstract of DOI:10.1246/cl.1989.117

The C19-C27 fragment of the ansa chain part of rifamycin S was stereoselectively sythesized from (4Z)-1,2-epoxy-3-methyl-4-hexene by reiterative use of stereoselective epoxidatation of cis-homoallylic alcohol and regioselective opening of the resulting ep

Full text of DOI:10.1246/cl.1989.117

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