New ionic liquids with the bis[bis(pentafluoroethyl)phosphinyl]imide anion, [(C2F5)2P(O)]2N--Synthesis and characterization

Article abstract of DOI:10.1016/j.jfluchem.2009.11.004

A new series of low melting and hydrophobic ionic liquids (ILs) containing the bis[bis(pentafluoroethyl)phosphinyl]imide anion, [(C₂F₅)₂P(O)]₂N^- (FPI), and ammonium, phosphonium, imidazolium, pyridinium or pyrrolidinium cations were prepared and characterized. Their density, viscosity, melting point, glass transition temperature, decomposition temperature and conductivity are discussed. Many of these ionic liquids are liquids at room temperature with melting points below 15 °C, viscosities below 110 mm² s^-1 and thermal stabilities above 300 °C.