Journal of the Chemical Society. Perkin transactions II p. 903 - 906 (1989)
Update date:2022-09-26
Topics:
Armesto, Diego
Horspool, William M.
Langa, Fernando
The acetophenone-sensitised irradiation of a series of 1-aryl-4,4-dimethyl-6,6-diphenyl-2-azahexa-2,5-dienes has been carried out.All undergo an aza-di-?-methane rearrangement to yield a cyclopropylimine.The determination of the quantum yields for the rearrangement showed a dependence on the nature of the substituents on the N-benzyl group and the reaction is most efficient with electron-withdrawing substituents.The linear relationship between log φ and ?+ suggests that there is an homoconjugative interaction between the benzyl group and the nitrogen ione-pair.
View MoreTaizhou Elitechemie MediPharma Technology Co.,Ltd.
Contact:+86-523-86810021
Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Suzhou SuKaiLu Chemical Technology Co., Ltd.
Contact:+86-512-62766020
Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province
ZHEJIANG CHEMICAL INDUSTRY INSTITUTE TECHNOLOGY CO.,LTD(expird)
Contact:86-575-82730298
Address:shangyu
Angelisun(Chongqing) Pharmaceutical Co., LTD.
Contact:+86-23-68030926-816
Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Jiangyin Tenghua Import&Export Co.,Ltd.
Contact:+86-510-86263875
Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Doi:10.1134/S1070427210090302
(2010)Doi:10.1021/om1003013
(2010)Doi:10.1016/j.tetlet.2010.10.025
(2010)Doi:10.1016/S0040-4039(00)95251-1
(1989)Doi:10.1002/ejoc.201000125
(2010)Doi:10.1039/c9nj04064a
(2019)
