The preparation of the aza-spirobicyclic system of discorhabdin C via an intramolecular phenolate alkylation

DOI: 10.1016/S0040-4039(00)97484-7

Source and publish data:

Tetrahedron Letters p. 3845 - 3848 (1990)

Update date:2022-08-03

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Authors:

Kublak Kublak

Confalone

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Article abstract of DOI:10.1016/S0040-4039(00)97484-7

A model study designed for the synthesis of the discorhabdin alkaloids is presented. The key reaction is the intramolecular para-phenolate alkylation of the mesyloxy aminonaphthoquinone 10 to afford the target tetracyclic system 11.

Full text of DOI:10.1016/S0040-4039(00)97484-7

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