Tetrahedron Letters p. 6697 - 6700 (1988)
Update date:2022-08-02
Topics:
Knochel, Paul
Xiao, Chaodong
Yeh, Ming Chang P.
The 1,1-diorganometallics of magnesium and zinc 1 are converted by the reaction with Me3SnCl to the 1,1-diorganometallics of tin and zinc 2 which are readily oxidized by dry air at -10 deg C to 0 deg C to afford the corresponding aldehydes and ketones 3 in 57-91percent yield.This mild oxidation reaction allows a new stereoselective approach to aldol products.An extension of the reaction to 1,1-diorganometallics of silicon and zinc is described.
View MoreWuhan Sunrise Pharmaceutical Technology Co., Ltd
Contact:+86-27-83314682
Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
Shenyang Xingzhenghe Chemical Co., Ltd.
Contact:024-23509232
Address:No. 33, Naner Road, Heping Dist.
SHANGHAI RC CHEMICALS CO.,LTD.
website:http://www.rcc.net.cn
Contact:+86-21-50322175
Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Changyi Xinxing Technology Development Co., Ltd.
Contact:0086-510-86651065(Time Zone:8),86651656
Address:94 Yingbinxilu WestRoad, Huangtu Town, Jiangyin City, Jiangsu, China
Contact:+86-20-32051076
Address:1105,Building A, International Business Incubator,Science City
Doi:10.1016/j.tet.2015.06.101
(2015)Doi:10.1246/cl.1992.781
(1992)Doi:10.3390/molecules25173791
(2020)Doi:10.1007/BF00958055
(1989)Doi:10.1002/jhet.107
(2009)Doi:10.1021/om9002363
(2009)
