Tetrahedron Letters p. 6697 - 6700 (1988)
Update date:2022-08-02
Topics:
Knochel, Paul
Xiao, Chaodong
Yeh, Ming Chang P.
The 1,1-diorganometallics of magnesium and zinc 1 are converted by the reaction with Me3SnCl to the 1,1-diorganometallics of tin and zinc 2 which are readily oxidized by dry air at -10 deg C to 0 deg C to afford the corresponding aldehydes and ketones 3 in 57-91percent yield.This mild oxidation reaction allows a new stereoselective approach to aldol products.An extension of the reaction to 1,1-diorganometallics of silicon and zinc is described.
View MoreContact:+86 21 5017 5386
Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
KAIYUAN CHEMICAL COMPANY LIMITED.
website:http://www.kaiyuanchem.com
Contact:+86-22-59891255/66/77
Address:B-2205, Kuangshi International Building, Yingbin Road, XiangLuo Bay Business District, Binhai New area, Tianjin, China.
Contact:+86-10-59484199
Address:No.58-A1026 Liangguan Street
Jinzhou Jiutai Pharmaceutical Co.,Ltd
Contact:+86-0416-5179890
Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning
YingYing Pharmaceutical Co.,Ltd
Contact:86-18854126208
Address:55#, yingxiongshan road
Doi:10.1016/j.tet.2015.06.101
(2015)Doi:10.1246/cl.1992.781
(1992)Doi:10.3390/molecules25173791
(2020)Doi:10.1007/BF00958055
(1989)Doi:10.1002/jhet.107
(2009)Doi:10.1021/om9002363
(2009)
