Photooxygenation of Arylmethylsilanes via Photoinduced Electron-Transfer

DOI: 10.1246/cl.1992.781

Source and publish data:

Chemistry Letters p. 781 - 784 (1992)

Update date:2022-08-02

Topics:

Authors:

Tamai, Toshiyuki

Mizuno, Kazuhiko

Hashida, Isao

Otsuji, Yoshio

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Article abstract of DOI:10.1246/cl.1992.781

The 9,10-dicyanoanthracene (DCA)-sensitized photooxygenation of arylmethylsilanes in acetonitrile and benzene gave aromatic aldehydes and aromatic carboxylic acids in a site-selective manner.This photoreaction involves exciplex and radical ions as reactive intermediates, depending on the solvents.

Full text of DOI:10.1246/cl.1992.781

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