Zur Umsetzung von Chlor-Methyl-Phenylethinyl-Silan mit Octacarbonyldicobalt; Reaktivitaetsstudien an 2-CCPh)Co2(CO)6>(Me)Si(H)(Cl)

Article abstract of DOI:10.1016/0022-328X(90)85368-9

(Me)(PhCC)Si(H)(Cl) (I) reacts selectively with Co2(CO)8 (II) to yield the η²-side-on coordinated compound (Me)(H)(Cl)Si<(η²-CCPh)Co2(CO)6> (III).Treatment of III with 0.5 mol of Co2(CO)8 yields the complex (Me)(Cl)Si<(η