Bulletin of the Chemical Society of Japan p. 2594 - 2598 (1992)
Update date:2022-09-26
Topics:
Shigemasa, Yoshihiro
Oikawa, Hiroshige
Ohral, Shin-ichiro
Sashiwa, Hitoshi
Saimoto, Hiroyuki
α,α-Disubstituted propargylic alcohols were transformed into enones by the catalysis with Ag(I) or Ag(I)-Me3SiCl under the mild conditions.This procedure provides a new synthetic method of α,β-unsaturated ketones having an oxygen function at α' position f
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