FUNCTIONALIZED CHLOROENAMINES IN AMINOCYCLOPROPANE SYNTHESIS III. SYNTHESIS AND ASSIGNMENT OF CONFIGURATION OF TWO ISOMERIC MORPHOLINOBICYCLO(3.1.0)HEXANE DERIVATIVES

DOI: 10.1016/S0040-4020(01)89230-9

Source and publish data:

Tetrahedron p. 3683 - 3694 (1989)

Update date:2022-07-29

Topics:

Authors:

Vilsmaier, Elmar

Adam, Rainer

Tetzlaff, Claus

Cronauer, Regina

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Article abstract of DOI:10.1016/S0040-4020(01)89230-9

Reaction of the acylated chloroenamine 7 with cyanide gave the endo-morpholino compound 11.The endo morpholino configuration of 11 was established by subsequent ring closure reactions generating tricyclic derivatives 14, 16 and 17.LiAlH4 reduction of 11 a

Full text of DOI:10.1016/S0040-4020(01)89230-9

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