PREPARATION AND REACTIONS OF 1,1,4,4-TETRAKIS(TRIMETHYLSILYL)BUTANE-1,4-DIYL DIANION

DOI: 10.1016/S0040-4039(00)88480-4

Source and publish data:

Tetrahedron Letters p. 6939 - 6942 (1988)

Update date:2022-08-05

Topics:

Authors:

Kira, Mitsuo

Hino, Takakazu

Kubota, Yasushi

Matsuyama, Naoko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)88480-4

Reduction of 1,1-bis(trimethylsilyl)ethylene by alkali metal led to the facile dimerization to the 1,1,4,4-tetrakis(trimethylsilyl)butane-1,4-diyl dianion which has been found to be utilized as a reagent for the Peterson reaction.

Full text of DOI:10.1016/S0040-4039(00)88480-4

Products guided by the article

Product name:1-Phenyl-2,2,5,5-tetrakis-trimethylsilanyl-silolane

Cas No:124080-37-1

R&D Labs maybe for 124080-37-1

NIGNXIA XINDACHANG TECHNOLOGY CO.,LTD

Contact:86-0951-7815345

Address:North side of Qiyuan Road, west side of Yuanfeng Highway, New Material Park, Ningdong Energy and Chemical Industry Base, Ningxia,China
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
Jitat Company Ltd

Contact:852-27701081

Address:Room 2509, New Tech Plaza, 34 Tai Yau St., San Po Kong, HK
Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China

Relevant to this article

Axial-to-Central Chirality Transfer for Construction of Quaternary Stereocenters via Dearomatization of BINOLs

Doi:10.1021/acs.orglett.9b03558
(2019)
Synthesis, electrochemical, magnetic, catalytic and antimicrobial studies of N-functionalized cyclam based trinuclear copper(II) and nickel(II) complexes

Doi:10.1007/s10847-009-9621-y
(2010)
Testing the functional tolerance of the Piers-Rubinsztajn reaction: A new strategy for functional silicones

Doi:10.1039/c0cc00369g
(2010)
Quinaphos and dihydro-quinaphos phosphine-phosphoramidite ligands for asymmetric hydrogenation

Doi:10.1002/chem.201000063
(2010)
Cycloisomerization between Aryl Enol Ether and Silylalkynes under Ruthenium Hydride Catalysis: Synthesis of 2,3-Disubstituted Benzofurans

Doi:10.1021/acs.orglett.7b00985
(2017)
A general methodology for the enantioselective synthesis of 1-substituted tetrahydroisoquinoline alkaloids

Doi:10.1002/ejoc.201000473
(2010)

Article Doi