Journal of Organic Chemistry p. 5854 - 5855 (1989)
Update date:2022-08-04
Topics:
Marshall, James A.
Robinson, Edward D.
Zapata, Antonio
The (R)-propargylic tributylstannylmethyl and glycolic acid ethers 4a, 4b, 5a and 5b rerrange to the (R)-allenylcarbinols 6a, 6b, 7a, and 7b of high ee upon treatment with n-BuLi or LDA, respectively, at low temperature.
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