REACTION OF DICYCLOPENTADIENYLYTTRIUM CHLORIDE WITH ALDEHYDES AND KETONES. A NOVEL CLEAVAGE REACTION OF Cp-Y ?-BOND

DOI: 10.1016/S0040-4039(00)88478-6

Source and publish data:

Tetrahedron Letters p. 6931 - 6934 (1988)

Update date:2022-08-02

Topics:

Authors:

Qian, Changtao

Qiu, Aineng

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)88478-6

Dicyclopentadienylyttrium chloride reacts with aldehydes and ketones at 80 deg C in DME, generating fulvenes in excellent yields, while at lower temperature affording, after hydrolysis, cyclopentadienyl substituted alcohols.

Full text of DOI:10.1016/S0040-4039(00)88478-6

Products guided by the article

Product name:1-cyclopentadienyl-cyclohexanol

Cas No:124186-93-2

R&D Labs maybe for 124186-93-2

CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County
Clearsynth Labs Limited

Contact:+91 - 22 - 26355700

Address:17, Lotus Business Park, Andheri West
Buffett (China) Holding Co.,Ltd

Contact:4006570891

Address:
Anhui Asahikasei Chemical Co., Ltd

Contact:86-551-4259770

Address:No. 88 Linquan Road Hefei Anhui China
Beijing Mashi Fine Chemical Co.,Ltd.

Contact:+86-10-61271592

Address:Room 506, Section B, Kaichi Mansion, Industrial Development

Relevant to this article

Intramolecular Diels-Alder Reactions of Sulfur-Substituted Dienes via 3-Sulfolenes

Doi:10.1021/jo00291a031
(1990)
Systematic electronic control in ambipolar compounds optimizes their photoluminescence properties: Synthesis, characterization, and device fabrication of four-coordinate boron compounds containing an N,O-chelating oxazolylphenolate ligand

Doi:10.1002/ejic.200900017
(2009)
Antibacterial activity and global reactivity descriptors of some newly synthesized unsymmetrical sulfamides

Doi:10.13005/ojc/320205
(2016)
Novel three-component reaction of perimidines with 1,3,5-triazines and carbonyl compounds in polyphosphoric acid. an efficient method for peri-annelation of a carbocyclic and pyridine ring

Doi:10.1007/s10593-012-1037-8
(2012)
Coplanar tetracyclic π-excess σ²P ligands

Doi:10.1002/ejic.201300342
(2013)
Novel Redox Reactions between Diaryl Disulfides and Iodoarenes

Doi:10.1021/jo00035a042
(1992)

Article Doi