REACTION OF DICYCLOPENTADIENYLYTTRIUM CHLORIDE WITH ALDEHYDES AND KETONES. A NOVEL CLEAVAGE REACTION OF Cp-Y ?-BOND

DOI: 10.1016/S0040-4039(00)88478-6

Source and publish data:

Tetrahedron Letters p. 6931 - 6934 (1988)

Update date:2022-08-02

Topics:

Authors:

Qian, Changtao

Qiu, Aineng

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Article abstract of DOI:10.1016/S0040-4039(00)88478-6

Dicyclopentadienylyttrium chloride reacts with aldehydes and ketones at 80 deg C in DME, generating fulvenes in excellent yields, while at lower temperature affording, after hydrolysis, cyclopentadienyl substituted alcohols.

Full text of DOI:10.1016/S0040-4039(00)88478-6

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