Reactivity of ortho-β-enaminone-phenyl palladium complexes. Insertion of CO into the Pd-C bond to give the first acyl C,N,O-pincer complexes. sequential insertion of dimethylacetylenedicarboxylate into the enaminone C-H bond and of isocyanide into the Pd-

Article abstract of DOI:10.1021/om1005403

Insertion of CO into the Pd-C_aryl bond of complexes [PdI{C ₆H₄{NHC(Me)CHC(O)Me}-2}(N^N)] afforded the benzoyl derivatives [PdI{C(O)C₆H₄{NHC(Me)CHC(O)Me}-2}(N^N)] [N^N = 4,4′-di-tert-butyl-2,2′-dipyrid