Stereoselective Synthesis and Absolute Stereochemistry of Sinefungin

DOI: 10.1021/jo00290a028

Source and publish data:

Journal of Organic Chemistry p. 948 - 955 (1990)

Update date:2022-08-05

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Authors:

Maguire, Martin P.

Feldman, Paul L.

Rapoport, Henry

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Article abstract of DOI:10.1021/jo00290a028

Sinefungin has been synthesized from D-ribose, L-ornithine, and adenine.L-Ornithine was converted to its δ-nitro analogue 10, which was coupled to the ribose derived aldehyde 11 by a potassium fluoride catalyzed nitro-aldol reaction.The resulting nitro al

Full text of DOI:10.1021/jo00290a028

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