Ligand electronic effect on reductive elimination of biphenyl from ci s-[Pt(Ph)2(diphosphine)] complexes bearing electron-poor diphosphine: Correlation study between experimental and theoretical results

DOI: 10.1021/om100073j

Source and publish data:

Organometallics p. 4025 - 4035 (2010)

Update date:2022-09-26

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Authors:

Korenaga, Toshinobu

Abe, Kayoko

Ko, Aram

Maenishi, Ryota

Sakai, Takashi

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Article abstract of DOI:10.1021/om100073j

The reductive elimination of biphenyl from cis-[Pt(Ph) ₂(diphosphine)] (3) was studied to clarify the electronic effects of diphosphine ligands on the reaction. Reaction kinetic data were evaluated in d₈-toluene within 80-110 °C usin

Full text of DOI:10.1021/om100073j

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