The Stereochemistry of a Substitution Reaction via an Episelenonium Ion: Retention by a 2-Pyridylseleno Group versus Scrambling by a Phenylseleno Group

DOI: 10.1039/c39890000530

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 530 - 531 (1989)

Update date:2022-08-04

Topics:

Authors:

Toshimitsu, Akio

Ito, Masaaki

Uemura, Sakae

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890000530

The first example of retention of configuration during substitution on a carbon atom situated β to an arylseleno group was discovered when using a 2-pyridylseleno (2-PySe) group.

Full text of DOI:10.1039/c39890000530

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(R)-2-pyridylseleno-1-phenylethanol

Cas No:124372-17-4

R&D Labs maybe for 124372-17-4

FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY

Contact:0086-0757-85609331

Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China
Nantong Auxin Electronic Technology Co., LTD

Contact:86-513-88760026

Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Hunan Haili Chemical Industry Co.,Ltd.

Contact:+86-731-85521860

Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China

Relevant to this article

STUDY OF THE ANOMERIC EFFECT IN 2-SUBSTITUTED 1,3-DITHIANES

Doi:10.1016/S0040-4020(01)87344-0
(1986)
Comparison of thiophene-pyrrole oligomers with oligothiophenes: A joint experimental and theoretical investigation of their structural and spectroscopic properties

Doi:10.1002/chem.201000143
(2010)
Novel nitric oxide-releasing derivatives of farnesylthiosalicylic acid: Synthesis and evaluation of antihepatocellular carcinoma activity

Doi:10.1021/jm1014814
(2011)
Complex Pyrrolidines via a Tandem Michael Reaction/1,3-Dipolar Cycloaddition Sequence. A Novel Method for the Generation of Unsymmetrical Azomethine Ylides

Doi:10.1021/jo00289a005
(1990)
Facile synthesis of a fluorescent cyclosporin A analogue to study cyclophilin 40 and cyclophilin 18 ligands

Doi:10.1021/ml1001272
(2010)
Improved palladium-catalysed synthesis of α-benzyl-β-keto esters

Doi:10.1055/s-0030-1258095
(2010)

Article Doi