Regioselective Cleavage of the Methylenedioxy Group: Conversion of (-)-Austrobailignan-5 to (-)-Dihydroguaiaretic Acid

DOI: 10.1021/jo00292a010

Source and publish data:

Journal of Organic Chemistry p. 1427 - 1429 (1990)

Update date:2022-08-03

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Authors:

Rao, Koppaka V.

Chattopadhyay, Sunil K.

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Article abstract of DOI:10.1021/jo00292a010

A method for the selective cleavage of a benzodioxole (methylenedioxy group) to a methoxyphenol through the use of a p-methylthiophenoxide ion is described.When the procedure was applied to a lignan derivative such as (-)-austrobailignan-5, the reaction w

Full text of DOI:10.1021/jo00292a010

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