Diphenylphosphinoyl-Substituted Ylides. 2. 1,3-Dipolar Cycloaddition of α-(Diphenylphosphinoyl)glycine Ester Imines. Dipolar Cycloaddition as the Rate-Determining Step

DOI: 10.1021/jo00300a023

Source and publish data:

Journal of Organic Chemistry p. 4069 - 4079 (1990)

Update date:2022-08-03

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Authors:

Es, J. J. G. Steven van

Wolde, Annemarie ten

Gen, Arne van der

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Article abstract of DOI:10.1021/jo00300a023

The thermal 1,3-dipolar cycloaddition of benzyl N-benzylidene-α-(diphenylphosphinoyl)glycinate (3) has been investigated as a general route to polyfunctionalized 2-(diphenylphosphinoyl)pyrrolidines.The Psyn and Panti dipoles 2A and 2B, generated via a for

Full text of DOI:10.1021/jo00300a023

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Product name:(2α,3α,4β,5β)-(+/-)-Phenylmethyl 3-cyano-2-(diphenylphosphinoyl)-4,5-diphenyl-2-pyrrolidinecarboxylate

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