
Comptes Rendus Chimie p. 803 - 811 (2010)
Update date:2022-09-26
Topics:
Lam, Oanh P.
Heinemann, Frank W.
Meyer, Karsten
The diamantane functionalized triazacyclononane ligand ( DiaArOH)3tacn (L3) has been synthesized and the reactivity of its U(III) metallated product [((DiaArO) 3tacn)U] (1) has been explored. Complex 1 promotes dichloromethane and azidotrimethylsilane activation to generate U(IV) complex [(( DiaArO)3tacn)U(Cl)] (2) and U(V) complex [(( DiaArO)3tacn) U(NTMS)] (3), respectively. Spectroscopic investigations of complexes 1, 2, and 3 will be discussed, along with molecular structures where possible.
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