Journal of Organometallic Chemistry p. 155 - 164 (1989)
Update date:2022-08-03
Topics:
Hu, Shui-Sheng
Weber, William P.
Photolysis of 1,1,2,2-tetramethyl-1,2-bis-(2'-thienyl)disilane (I) in methanol/benzene leads to dimethyl-bis-(2'-thienyl)silane (III), 2-methoxydimethylsilylthiophene (IV) and 2-dimethylsilylthiophene (V) as a major products.The mechanism of this reaction, has been explored by use of methanol-d4.The predominant pathway leading to IV and V appears to involve direct reaction of methanol with the photoexcited state of I.
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(2012)Doi:10.1007/BF00949611
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(1989)
