STEREOSELECTIVE ARYLATIONS USING METAL PHENOLATES. COMPLEMENTARY SYNTHESIS OF 5-C-ARYLXYLOFURANOSE DERIVATIVES OF EITHER L-IDO OR D-GLUCO CONFIGURATION

DOI: 10.1016/S0040-4020(01)80115-0

Source and publish data:

Tetrahedron p. 2869 - 2874 (1989)

Update date:2022-08-03

Topics: Stereoselective

Authors:

Cornia, Mara

Casiraghi, Giovanni

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Article abstract of DOI:10.1016/S0040-4020(01)80115-0

The arylation of 3-O-methyl-1,2-O-isopropylidene-α-D-xylo-pentodialdofuranose (2) at the aldehyde centre by means of bromomagnesium or triisopropoxytitanium salts of phenols 1 provides a simple access to 5-C arylxylofuranoses 3 and 4 of either L-ido or D-

Full text of DOI:10.1016/S0040-4020(01)80115-0

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Product name:(5S)-1,2-O-isopropylidene-3-O-methyl-5-(2-hydroxyphenyl)-α-D-xylofuranose

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