SYNTHESIS OF A HIGHER CARBON SUGAR VIA DIRECTED ALDOL CONDENSATION

DOI: 10.1016/S0040-4039(01)80398-1

Source and publish data:

Tetrahedron Letters p. 2359 - 2362 (1989)

Update date:2022-09-26

Topics:

Authors:

Jarosz, Slawomir

Fraser-Reid, Bert

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Article abstract of DOI:10.1016/S0040-4039(01)80398-1

3-O-Benzyl-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexadialdo-1,4-furanose (2) upon treatment with LiN(TMS)2 at -50 deg C furnished the enolate which reacted with methyl 2,3,4-tri-O-benzyl-α-D-glucopyranoside-6-ulose (5) to afford two erythro aldols 3 and 4

Full text of DOI:10.1016/S0040-4039(01)80398-1

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