NEW SUBSTITUTION REACTION OF ALLYLIC NITRO COMPOUNDS. REGIOSELECTIVE REPLACEMENT OF NITRO GROUP IN CYCLIC α-(NITROALKYL)ENONES BY NUCLEOPHILES

DOI: 10.1016/S0040-4039(01)80414-7

Source and publish data:

Tetrahedron Letters p. 2413 - 2416 (1989)

Update date:2022-08-04

Topics:

Authors:

Tamura, Rui

Tamai, Shinobu

Suzuki, Hitomi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)80414-7

Regioselective replacement of nitro group in cyclic α-(nitroalkyl)-enones by various nucleophiles such as stabilized carbanions, amine, NaN3, PhSO2Na and PhSNa provides the overall S_N2 type products.

Full text of DOI:10.1016/S0040-4039(01)80414-7

Products guided by the article

Product name:2-[2-Eth-(Z)-ylidene-3-oxo-cyclohexyl]-malonic acid dimethyl ester

Cas No:125066-10-6

R&D Labs maybe for 125066-10-6

Sinonine Industry Co.,Ltd

Contact:86+21-56421993

Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
xujianqiang

Contact:86-21-57725962

Address:shanghai
Mollt Biochem Co., Ltd(expird)

Contact:+86-21-38682181

Address:shanghai ,china
Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513

Relevant to this article

Divergent, stereoselective access to heterocyclic α,α-quaternary- and β^2,3,3-amino acid derivatives from a N-Pmp-protected Orn-derived β-lactam

Doi:10.1039/c5ob00429b
(2015)
Synthesis of new enantiomeric 1,2-diamines containing a myrtenyl fragment

Doi:10.1134/S1070428007030037
(2007)
Synthesis and biological activities of azalamellarins

Doi:10.1002/asia.201000237
(2010)
Supramolecular Paradigm for Capture and Co-Precipitation of Gold(III) Coordination Complexes

Doi:10.1002/chem.202003680
(2021)
SYNTHESIS EXPERIMENTS IN THE EMETINE GROUP.

Doi:10.1002/ardp.19642970404
(1964)
Doi:10.1007/BF00956540
()

Article Doi