SYNTHESE CYCLOPROPENIQUE TOTALE D'UN TRIQUINANE NATUREL ANGULAIRE, LE (+/-)-SILPHINENE

DOI: 10.1016/S0040-4039(00)99432-2

Source and publish data:

Tetrahedron Letters p. 3533 - 3536 (1989)

Update date:2022-08-04

Topics: Yield NMR spectroscopy Reagents Catalyst Chemical Synthesis Stereoselectivity Synthese cyclopropenique totale

Authors:

Franck-Neumann, M.

Miesch, M.

Lacroix, E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)99432-2

(+/-)-Silphinene, a natural angular triquinane has been synthesized, starting from 3,3-dimethyl-methoxycarbonylcyclopropene.The ring A of the skeleton results from the cycloaddition of the cyclopropene with the enamine 1, followed by solvolytic ring cleav

Full text of DOI:10.1016/S0040-4039(00)99432-2

Products guided by the article

Product name:(1S,2R,4S,5R)-8-Benzyloxy-3,3-dimethyl-1-morpholin-4-yl-tricyclo[3.3.0.0^2,4]octane-2-carboxylic acid methyl ester

Cas No:125184-66-9

R&D Labs maybe for 125184-66-9

ShangHai Original Economy-Trade Develop Co.,Ltd.,

Contact:86-21-68552131

Address:shanghai
Shanghai Bojing Chemical Co., Ltd.

Contact:021-37122233

Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
Sanming Coffer Fine Chemical Industrial Co., Ltd

website:http://www.cofferxm.com/

Contact:+86-598-5853979

Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China
Hawks Chemical

Contact:+44 (0)161 367 9441

Address:
Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai

Relevant to this article

N-Alkylated 2,3,3-trimethylindolenines and 2-methylbenzothiazoles. Potential lead compounds in the fight against Saccharomyces cerevisiae infections Dedication in memory of the late Derek Bennett 17-07-1931 to 05-04-2013.

Doi:10.1016/j.ejmech.2013.03.031
(2013)
Application of stabilized sugar-derived phosphoranes in the synthesis of higher carbon monosaccharides. First synthesis of a C₂₁-dialdose

Doi:10.1016/S0040-4020(98)00021-0
(1998)
Synthesis of small molecules with high scaffold diversity: Exploitation of metathesis cascades in combination with inter-and intramolecular diels-alder reactions

Doi:10.1002/chem.201000707
(2010)
3-Formylchromones, acylpyruvates, and chalcone as valuable substrates for the syntheses of fused pyridines

Doi:10.1055/s-0029-1218842
(2010)
Convenient synthesis of tetrahydro-γ-carbolines and tetrahydroquinolines through a chemo- and regioselectivity switch by a broonsted acid catalyzed, one-pot, multicomponent reaction

Doi:10.1002/ejoc.201000853
(2010)
Synthesis, spectroscopic properties, structural characterization and electrochemistry of mixed ligand complexes of copper(I) halide with PPh ₃and naphthylazoimidazole

Doi:10.1016/j.poly.2010.04.007
(2010)

Article Doi