Tetrahedron Letters p. 3533 - 3536 (1989)
Update date:2022-08-04
Topics: Yield NMR spectroscopy Reagents Catalyst Chemical Synthesis Stereoselectivity Synthese cyclopropenique totale
Franck-Neumann, M.
Miesch, M.
Lacroix, E.
(+/-)-Silphinene, a natural angular triquinane has been synthesized, starting from 3,3-dimethyl-methoxycarbonylcyclopropene.The ring A of the skeleton results from the cycloaddition of the cyclopropene with the enamine 1, followed by solvolytic ring cleav
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