SYNTHESE CYCLOPROPENIQUE TOTALE D'UN TRIQUINANE NATUREL ANGULAIRE, LE (+/-)-SILPHINENE

DOI: 10.1016/S0040-4039(00)99432-2

Source and publish data:

Tetrahedron Letters p. 3533 - 3536 (1989)

Update date:2022-08-04

Topics: Yield NMR spectroscopy Reagents Catalyst Chemical Synthesis Stereoselectivity Synthese cyclopropenique totale

Authors:

Franck-Neumann, M.

Miesch, M.

Lacroix, E.

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Article abstract of DOI:10.1016/S0040-4039(00)99432-2

(+/-)-Silphinene, a natural angular triquinane has been synthesized, starting from 3,3-dimethyl-methoxycarbonylcyclopropene.The ring A of the skeleton results from the cycloaddition of the cyclopropene with the enamine 1, followed by solvolytic ring cleav

Full text of DOI:10.1016/S0040-4039(00)99432-2

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