The cyclobutenic way to triquinanes. Synthesis of (±) silphinene

DOI: 10.1016/S0040-4039(00)71256-1

Source and publish data:

Tetrahedron Letters p. 2135 - 2136 (1991)

Update date:2022-08-05

Topics:

Authors:

Franck-Neumann, Michel

Miesch, Michel

Gross, Laurence

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)71256-1

The easily accessible alcohol 2 is oxidized, after protection, to the allylic alcohol 3. The benzyl ether of this diquinanic alcohol is transformed into the triquinanic precursor 9 of (±) Silphinene, using a similar reaction sequence as described previous

Full text of DOI:10.1016/S0040-4039(00)71256-1

Products guided by the article

Product name:{(3R,3aS,6R)-6-Benzyloxy-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-2,2-dimethyl-2,3,3a,4,5,6-hexahydro-pentalen-1-yl}-methanol

Cas No:125184-78-3

R&D Labs maybe for 125184-78-3

Jiangsu Allyrise Pharmaceutical Co., Ltd.(expird)

Contact:+86-523-86818997

Address:Taizhou,Jiangsu Province,CHINA
Sanming Coffer Fine Chemical Industrial Co., Ltd

website:http://www.cofferxm.com/

Contact:+86-598-5853979

Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China
Anhui Dexinjia Biopharm Co., Ltd

Contact:+86-531-82375818

Address:9 Hexie Road, kaifaqu, Taihe
Shanghai Bosman Industrial Co., Ltd

Contact:86-21-63065878-8006

Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China

Relevant to this article

Benzyne-Oxazole Cycloadducts: Isolation and Retro-Diels-Alder Reactions

Doi:10.1021/jo00290a025
(1990)
S_NAr-based, facile synthesis of a library of benzothiaoxazepine-1,1′-dioxides

Doi:10.1021/cc1001023
(2010)
Isolation of a new cycloartanoid triterpene from leaves of Lansium domesticum novel skin-tumor promotion inhibitors

Doi:10.1016/S0040-4039(01)93813-4
(1989)
REGIOSELECTIVE SYNTHESIS OF HIGHLY SUBSTITUTED ARYLSILANES BY THE REACTION OF THE TRIMETHYLSILYL-SUBSTITUTED VINYLALLENONES WITH ENAMINES

Doi:10.1016/S0040-4039(00)99452-8
(1989)
Bis(imino)aryl NCN pincer aluminum and zinc complexes: Synthesis, characterization, and catalysis on L -lactide polymerization

Doi:10.1021/om100344p
(2010)
Novel acyclic diaminocarbene ligands with increased steric demand and their application in gold catalysis

Doi:10.1021/ol102018z
(2010)

Article Doi