The cyclobutenic way to triquinanes. Synthesis of (±) silphinene

DOI: 10.1016/S0040-4039(00)71256-1

Source and publish data:

Tetrahedron Letters p. 2135 - 2136 (1991)

Update date:2022-08-05

Topics:

Authors:

Franck-Neumann, Michel

Miesch, Michel

Gross, Laurence

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Article abstract of DOI:10.1016/S0040-4039(00)71256-1

The easily accessible alcohol 2 is oxidized, after protection, to the allylic alcohol 3. The benzyl ether of this diquinanic alcohol is transformed into the triquinanic precursor 9 of (±) Silphinene, using a similar reaction sequence as described previous

Full text of DOI:10.1016/S0040-4039(00)71256-1

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Product name:{(3R,3aS,6R)-6-Benzyloxy-3-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-2,2-dimethyl-2,3,3a,4,5,6-hexahydro-pentalen-1-yl}-methanol

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