Tetrahedron Letters p. 3541 - 3544 (1989)
Update date:2022-08-04
Topics:
Cahiez, Gerard
Alami, Mouad
Copper-catalyzed conjugate addition of organomanganese chlorides to conjugated enones in THF, at 0 deg C, leads to the 1,4-addition products in high yields.The scope of the reaction is very large and the results are generally better than those obtained from organomagnesium compounds in the presence of a copper salts as well as from organocopper or cuprate reagents.Furthermore organomanganese chlorides are indisputably cheaper and more stable than the latter.
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Doi:10.1016/S0040-4039(00)99391-2
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