Tetrahedron Letters p. 2677 - 2680 (1989)
Update date:2022-08-03
Topics:
Bonini, Bianca F.
Maccagnani, Gaetano
Masiero, Stefano
Mazzanti, Germana
Zani, Paolo
The reaction of R-(-)-methyl-α-naphtyl-phenylsilyl phenyl thioketone 1 with organolithium derivatives and Grignard reagents gives the α-silylsulphides 3 with medium to good levels of asymmetric induction.The asymmetry induced at the α-carbon is retained in the subsequent desilylation.
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