Organometallics p. 1336 - 1337 (1990)
Update date:2022-09-26
Topics:
Elliot, David J.
Ferguson, George
Holah, David G.
Hughes, Alan N.
Jennings, Michael C.
Magnuson, Vincent R.
Potter, David
Puddephatt, Richard J.
The complex [CoRh(CO)3(μ-dppm)2] (1), formed directly from Co(II) and Rh(III), reacts with CHCl3 or HgCl2 to give [CoRh(μ-Cl)(CO)2(μ-CO)(μ-dppm)2]+ (3a), with I2 to give [CoRh(μ-I)(CO)2(μ-CO)(μ-dppm)2]+ (3b), with sulfur to give [CoRh(μ-S)(CO)2(μ-CO)(μ-dppm)2] (3C), with H+ to give [CoRh(μ-H)(CO)3(μ-dppm)2]+ (4), and with Ph2PH to give [CoRh(μ-H)(μ-PPh2)(CO)2(μ-dppm)2] (5), all with retention of the heterobimetallic unit. The complexes have been characterized by spectroscopy and, for 1 and 5, by X-ray structure analysis.
View MoreDayang Chem (Hangzhou) Co.,Ltd.
website:http://www.dycnchem.com
Contact:+86-571-88938639
Address:9/F, Unit 2 Changdi Torch Building, 259# WenSan Road, Xihu District, Hangzhou City 310012, P.R.China
Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.
Contact:+86-576-87501888 / 87501988
Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
Beijing Green Guardee Technology CO,.LTD
Contact:+86-10-69706062
Address:F2 BLdj,5 No.37 Chaoqian Road
Contact:+86-28-88523492
Address:714rooms of Time Square, Pujiang County
Shijiazhuang Sdyano Fine Chemical Co., Ltd
Contact:+86-311-89830448
Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
Doi:10.3762/bjoc.14.207
(2018)Doi:10.1016/0022-328X(93)83012-K
(1993)Doi:10.1021/om100673e
(2010)Doi:10.1016/j.bmc.2010.08.028
(2010)Doi:10.1016/j.tet.2010.09.009
(2010)Doi:10.1016/j.cclet.2010.03.016
(2010)
