Organometallics p. 1336 - 1337 (1990)
Update date:2022-09-26
Topics:
Elliot, David J.
Ferguson, George
Holah, David G.
Hughes, Alan N.
Jennings, Michael C.
Magnuson, Vincent R.
Potter, David
Puddephatt, Richard J.
The complex [CoRh(CO)3(μ-dppm)2] (1), formed directly from Co(II) and Rh(III), reacts with CHCl3 or HgCl2 to give [CoRh(μ-Cl)(CO)2(μ-CO)(μ-dppm)2]+ (3a), with I2 to give [CoRh(μ-I)(CO)2(μ-CO)(μ-dppm)2]+ (3b), with sulfur to give [CoRh(μ-S)(CO)2(μ-CO)(μ-dppm)2] (3C), with H+ to give [CoRh(μ-H)(CO)3(μ-dppm)2]+ (4), and with Ph2PH to give [CoRh(μ-H)(μ-PPh2)(CO)2(μ-dppm)2] (5), all with retention of the heterobimetallic unit. The complexes have been characterized by spectroscopy and, for 1 and 5, by X-ray structure analysis.
View MoreShuanghe Bio-Technology Limited(expird)
Contact:+86-571-61710758,18968016640
Address:Jinqiao north road 916# Fuyang
MedicalChem(Yancheng)Manuf.Co.,Ltd.
Contact:+86-515-84383366
Address:Touzeng BinHai, YanCheng City, JiangSu Province, China
Shanghai Yuanding Chem. Sci. & Tech. Co., Ltd.
website:http://www.shydtec.com
Contact:86-21-57721279
Address:Science and Technology Park, Songjiang District, Shanghai, China
Changzhou naidechemical Co.Ltd
Contact:+86-519-82589807
Address:NO.25,Houyang street,Jintan,Changzhou City
website:http://www.antimex.com
Contact:0086-21-50563169
Address:Room1027,No.Jinyu Road,Pudong
Doi:10.3762/bjoc.14.207
(2018)Doi:10.1016/0022-328X(93)83012-K
(1993)Doi:10.1021/om100673e
(2010)Doi:10.1016/j.bmc.2010.08.028
(2010)Doi:10.1016/j.tet.2010.09.009
(2010)Doi:10.1016/j.cclet.2010.03.016
(2010)
