Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1755 - 1757 (1989)
Update date:2022-08-04
Topics:
Sinyashina, T. N.
Mironov, V. F.
Ofitserov, E. N.
Konovalova, I. V.
Pudovik, A. N.
The reaction of 2-tert-butoxy-4,5-benzo-1,3,2-dioxaphospholane with tribromoacetaldehyde proceeds by initial halophilic attack on the bromine atom, leading to a product with retention of the P-Br bond (pyrocatechol bromophosphate) and an anion exchange product (pyrocatechol dibromovinylphosphate), and by initial attack at the carbon atom of the C=O group, which is accompanied by the elimination of isobutylene to form an α-hydroxyphosphonate.
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