A SELECTIVE ONE-CARBON RING EXPANSION REACTION OF 1-SILOXYCYCLOALKANECARBALDEHYDES CATALYZED BY A LEWIS ACID

DOI: 10.1016/S0040-4039(01)80707-3

Source and publish data:

Tetrahedron Letters p. 4267 - 4270 (1989)

Update date:2022-08-04

Topics:

Authors:

Matsuda, Toyoharu

Tanino, Keiji

Kuwajima, Isao

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Article abstract of DOI:10.1016/S0040-4039(01)80707-3

Under the influence of a Lewis acid, 1-siloxycycloalkanecarbaldehydes undergo one-carbon ring enlargement reaction to afford the corresponding 2-siloxycycloalkanones in good yields.Regiochemistry of this rearrangement reaction has also been examined, and

Full text of DOI:10.1016/S0040-4039(01)80707-3

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