Organic and Biomolecular Chemistry p. 5620 - 5627 (2010)
Update date:2022-07-29
Topics:
Mangalum, Anshuman
Gilliard Jr., Robert J.
Hanley, Jessica M.
Parker, Austa Marie
Smith, Rhett C.
Chromophores ranging from simple small molecule π-conjugated systems comprised of phenylene ethynylene or fluorenylethynyl units to cross-conjugated Bunz-type cruciforms have been derivatized to include 1,3- bis(dimethylaminomethyl)phenyl moieties. The photophysical responsiveness of these diamino-substituted chromophores to metal ions has been examined. Both emission enhancement (turn-on) and ratiometric fluorescence detection of Cu 2+ and Zn2+ ions have been achieved in THF.
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