Chemical Communications p. 394 - 396 (2011)
Update date:2022-08-02
Topics:
Winter, Philipp
Vaxelaire, Carine
Heinz, Christoph
Christmann, Mathias
The Cu-catalyzed synthesis of skipped 1,4-dienes from allylic acetates and vinyl-Grignard reagents is key to bidirectional modifications of acyclic terpene acetates. As a result, trisubstituted double bond containing subunits can be readily transferred into complex polyketides from inexpensive bulk terpenes.
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