Iron-catalyzed oxidative addition of alkoxycarbonyl radicals to alkenes with carbazates and air

DOI: 10.1002/anie.201005574

Source and publish data:

Angewandte Chemie - International Edition p. 10154 - 10157 (2010)

Update date:2022-09-26

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Authors:

Taniguchi, Tsuyoshi

Sugiura, Yuki

Zaimoku, Hisaaki

Ishibashi, Hiroyuki

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Article abstract of DOI:10.1002/anie.201005574

Clean and simple: Alkoxycarbonyl radicals generated from carbazates by iron catalysis in air underwent addition to a variety of alkenes to give the corresponding β-hydroxyesters (see scheme). The simple experimental procedure for this transformation has the added advantage that the reagents are environmentally friendly. R¹,R²=alkyl, alkynyl, aryl, CO₂Et; [Fe(Pc)]=iron phthalocyanine. Copyright

Full text of DOI:10.1002/anie.201005574

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