1-Alkyl-2-trifluoromethylaziridines: The bacisity and ring-opening reactions under the action of acids

DOI: 10.1007/BF02496214

Source and publish data:

Russian Chemical Bulletin p. 1136 - 1139 (1997)

Update date:2022-08-04

Topics:

Authors:

Karimova

Teplenicheva

Kolomiets

Fokin Fokin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF02496214

The basicity of 1-alkyl-2-trifluoromethylaziridines is -two orders of magnitude lower than that of non-fluorinated analogs. Aziridines are stable to H₂S and AcOH, but react with AcSH, HCl, HBr, H₂SO₄, TsOH, and picric acid to give products of ring-opening.

Full text of DOI:10.1007/BF02496214

Products guided by the article

Product name:2-(benzylamino)-3,3,3-trifluoropropan-1-ol

Cas No:126536-03-6

R&D Labs maybe for 126536-03-6

Jiangsu Mingchem Corporation

website:http://www.mingchem.com/en/index

Contact:0519-85170101-802

Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
Jewim Pharmaceutical (Shandong) Co., Ltd

Contact:+8615621883869

Address:山东省泰安市高新技术产业开发区配天门大街西首
HANGZHOU ICH BIOFARM CO.,LTD

Contact:+86-571-28186845

Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China

Relevant to this article

Differing reactions of functionalized hydrocarbons with Cp*M(NO)(alkyl)( η³-allyl) complexes of molybdenum and tungsten

Doi:10.1021/om100909m
(2011)
Organocatalytic sequential Michael reactions: Stereoselective synthesis of multifunctionalized tetrahydroindan derivatives

Doi:10.1021/ol1029832
(2011)
Porphyrins as Photoredox Catalysts in Csp²-H Arylations: Batch and Continuous Flow Approaches

Doi:10.1021/acs.joc.8b02355
(2018)
Copper-TEMPO-catalyzed synthesis of α-ketoamides: Via tandem sp³C-H aerobic oxidation and amination of phenethyl alcohol derivatives

Doi:10.1039/c6ob01387b
(2016)
PALLADIUM-CATALYZED PHOSPHORYLATION OF ALKENYL TRIFLATES

Doi:10.1016/S0040-4039(01)80576-1
(1989)
SYNTHESIS AND CHOLINE ESTERASE HYDROLYSIS OF O-ACYLATED ALKYLCHLOROFORMOXIMES

Doi:10.1007/BF00764612
(1989)

Article Doi