1-Alkyl-2-trifluoromethylaziridines: The bacisity and ring-opening reactions under the action of acids

DOI: 10.1007/BF02496214

Source and publish data:

Russian Chemical Bulletin p. 1136 - 1139 (1997)

Update date:2022-08-04

Topics:

Authors:

Karimova

Teplenicheva

Kolomiets

Fokin Fokin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF02496214

The basicity of 1-alkyl-2-trifluoromethylaziridines is -two orders of magnitude lower than that of non-fluorinated analogs. Aziridines are stable to H₂S and AcOH, but react with AcSH, HCl, HBr, H₂SO₄, TsOH, and picric acid to give products of ring-opening.

Full text of DOI:10.1007/BF02496214

Products guided by the article

Product name:2-(benzylamino)-3,3,3-trifluoropropan-1-ol

Cas No:126536-03-6

R&D Labs maybe for 126536-03-6

HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD

Contact:+86-571-88932183

Address:Hangzhou
Zouping Mingxing Chemical Co.,Ltd.

website:http://www.zoutong.com.cn

Contact:86-543-2240068 2240067

Address:428 Daixi Third Road Zouping County Shandong Province China
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
shanghai Tauto Biotech Co., Ltd

website:http://www.tautobiotech.com/en/index.htm

Contact:+86-21-51320588 ext. 8025

Address:No. 326, Aidisheng Rd , Zhangjiang Hi-tech Park, Shanghai , P.R.CHINA

Relevant to this article

Differing reactions of functionalized hydrocarbons with Cp*M(NO)(alkyl)( η³-allyl) complexes of molybdenum and tungsten

Doi:10.1021/om100909m
(2011)
Organocatalytic sequential Michael reactions: Stereoselective synthesis of multifunctionalized tetrahydroindan derivatives

Doi:10.1021/ol1029832
(2011)
Porphyrins as Photoredox Catalysts in Csp²-H Arylations: Batch and Continuous Flow Approaches

Doi:10.1021/acs.joc.8b02355
(2018)
Copper-TEMPO-catalyzed synthesis of α-ketoamides: Via tandem sp³C-H aerobic oxidation and amination of phenethyl alcohol derivatives

Doi:10.1039/c6ob01387b
(2016)
PALLADIUM-CATALYZED PHOSPHORYLATION OF ALKENYL TRIFLATES

Doi:10.1016/S0040-4039(01)80576-1
(1989)
SYNTHESIS AND CHOLINE ESTERASE HYDROLYSIS OF O-ACYLATED ALKYLCHLOROFORMOXIMES

Doi:10.1007/BF00764612
(1989)

Article Doi