Intramolecular Diels-Alder Approach to Cadinane and Amorphane Sesquiterpenes

DOI: 10.1021/jo00299a040

Source and publish data:

Journal of Organic Chemistry p. 3912 - 3917 (1990)

Update date:2022-08-03

Topics:

Authors:

Davidson, Bradley S.

Plavcan, Kathleen A.

Meinwald, Jerrold

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Article abstract of DOI:10.1021/jo00299a040

A synthetic route to both cadinane and amorphane type sesquiterpenes is described.Successful implementation of this route showed the structures previously considered for cadinenal (1) and dehydrocadinenal (2) to be incorrect, but confirmed both the relative and absolute configurations proposed for pernetic acid C (3) and pernetic acid B (4).

Full text of DOI:10.1021/jo00299a040

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