Controlling the Stereochemistry of the Ring Junction in Hexahydrodibenzofurans

DOI: 10.1021/jo00021a042

Source and publish data:

Journal of Organic Chemistry p. 6180 - 6188 (1991)

Update date:2022-07-30

Topics:

Authors:

Rupprecht, Kathleen M.

Boger, Joshua

Hoogsteen, Karst

Nachbar, Robert B.

Springer, James P.

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Article abstract of DOI:10.1021/jo00021a042

The 8-hydroxy-1,2,3,4,4a,9b-hexahydrodibenzofuran-3-one formed during the acid-catalyzed rearrangement of 1,4,4a,8a-tetrahydro-1-methoxy-1,4-ethanonaphthalene-5,8-dione is, contrary to published reports, exclusively the cis isomer by X-ray crystallography

Full text of DOI:10.1021/jo00021a042

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