Stereoselective synthesis of gem-disubstituted cyclopropanes from gem-dibromocyclopropanes

DOI: 10.1016/S0040-4039(01)93848-1

Source and publish data:

Tetrahedron Letters p. 6039 - 6040 (1989)

Update date:2022-08-05

Topics:

Authors:

Harada Harada

Katsuhira

Hattori Hattori

Oku Oku

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Article abstract of DOI:10.1016/S0040-4039(01)93848-1

The title reaction is realized by utilizing an intramolecular alkylation reaction of zincate carbenoids followed by a Pd (0)-catalyzed coupling reaction with acyl, aryl, and alkenyl halides.

Full text of DOI:10.1016/S0040-4039(01)93848-1

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Product name:r-1-butyl-1-(2-propenyl)-c-2-phenylcyclopropane

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