Stereoselective synthesis of gem-disubstituted cyclopropanes from gem-dibromocyclopropanes

DOI: 10.1016/S0040-4039(01)93848-1

Source and publish data:

Tetrahedron Letters p. 6039 - 6040 (1989)

Update date:2022-08-05

Topics:

Authors:

Harada Harada

Katsuhira

Hattori Hattori

Oku Oku

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)93848-1

The title reaction is realized by utilizing an intramolecular alkylation reaction of zincate carbenoids followed by a Pd (0)-catalyzed coupling reaction with acyl, aryl, and alkenyl halides.

Full text of DOI:10.1016/S0040-4039(01)93848-1

Products guided by the article

Product name:r-1-butyl-1-(2-propenyl)-c-2-phenylcyclopropane

Cas No:126773-52-2

R&D Labs maybe for 126773-52-2

Beijing Green Guardee Technology CO,.LTD

Contact:+86-10-69706062

Address:F2 BLdj,5 No.37 Chaoqian Road
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Nanjing Samwon International Limited

Contact:+86-25-84873444

Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Shanghai Xinda Pharmaceuticals Co., Ltd.

Contact:86-21-33692333-8008

Address:999 Linxian Road, Jinshan Industrial Park, Shanghai, China

Relevant to this article

New umpolung catalysts: Reactivity and selectivity of terpenol-based lithium phosphonates in enantioselective benzoin-type couplings

Doi:10.1002/ejoc.201001295
(2011)
Novel Stereoselective route to Cis-chrysanthemic acid

Doi:10.1016/S0040-4039(00)82293-5
(1988)
Synthesis and biological evaluation of novel dihydro-aryl/alkylsulfanyl- cyclohexylmethyl-oxopyrimidines (S-DACOs) as high active anti-HIV agents

Doi:10.1016/j.bmcl.2010.12.003
(2011)
Catalytic dehydrative S-allylation of cysteine-containing peptides in aqueous media toward lipopeptide chemistry

Doi:10.1021/jo102278m
(2011)
Heteroleptic half-sandwich Ru(II), Rh(III) and Ir(III) complexes based on 5-ferrocenyldipyrromethene

Doi:10.1016/j.jorganchem.2010.09.070
(2011)
Convenient one pot preparation of acylated phosphinimines and aminophosphonium salts from the versatile triphenylphosphonium and lithium azayldiide Ph₃P=N-Li

Doi:10.1080/10426509808545488
(1998)

Article Doi