Stereoselective Δ4-Pipecolic Acid Synthesis via Alkylation of a Vinyl N-Boc-iminium Ion Derived from Baikiain

DOI: 10.1016/S0040-4039(00)76188-0

Source and publish data:

Tetrahedron Letters p. 5751 - 5754 (1989)

Update date:2022-07-31

Topics:

Authors:

Hanson, Gunnar J.

Russell, Mark A.

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Article abstract of DOI:10.1016/S0040-4039(00)76188-0

Stereoselective functionalization of Boc-(+/-)-Baikiain was demonstrated via seleno- and iodolactonization to afford lactones 5.These were converted to enecarbamate 7, which undergoes regio- and stereoselective alkylation at C-6 upon treatment with organo

Full text of DOI:10.1016/S0040-4039(00)76188-0

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