Asymmetric Synthesis XVII : Facile Generation of a Chiral Azomethine Ylide via the CN(R,S) Method

DOI: 10.1016/S0040-4039(01)93467-7

Source and publish data:

Tetrahedron Letters p. 5133 - 5136 (1989)

Update date:2022-07-29

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Authors:

Rouden, Jacques

Royer, Jacques

Husson, Henri-Philippe

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Article abstract of DOI:10.1016/S0040-4039(01)93467-7

(-)-N-cyanomethyl-4-phenyl-1,3-oxazolidine, prepared in one step from R-(-)-phenylglycinol, gives a chiral azomethine ylide on treatment with TMSOTf and (iPr)2NEt.This ylide undergoes 1,3-dipolar cycloaddition reactions with activated olefins under very m

Full text of DOI:10.1016/S0040-4039(01)93467-7

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Product name:1,4-Bis-((R)-1-phenyl-2-trimethylsilanyloxy-ethyl)-piperazine-2,5-dicarbonitrile

Cas No:127196-22-9

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