Tetrahedron Letters p. 7253 - 7256 (1989)
Update date:2022-08-02
Topics: Synthesis Novel Unsymmetrical
Ayyangar
Naik
Srinivasan
A novel synthesis of unsymmetrical azo aromatics inaccessible by diazo-coupling reaction is reported. The synthesis involved the reaction of acetanilides with nitroarenes under moderate reaction conditions. A reaction pathway via a nitrosoarene intermediate involving elimination of the elements of the acetate anion, is proposed.
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