Carbohydrate Research p. 163 - 170 (1989)
Update date:2022-08-03
Topics:
Vicent, Cristina
Coteron, Jose-Miguel
Jimenez-Barbero, Jesus
Martin-Lomas, Manuel
Penades, Soledad
The condensation of acetylated 1-(endo-cyano)ethylidene derivatives having the D-gluco, D-xylo, and D-galacto configurations (2-6) with a primary (8) and a secondary (9) trityl derivative was more rapid than for the corrensponding exo-isomers.This difference in reactivity is explained on the basis of differences in conformation.
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