Palladacycle mediated synthesis of cyano-functionalized chiral 1,2-diphosphine and subsequent functional group transformations

DOI: 10.1016/j.jorganchem.2010.10.029

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Journal of Organometallic Chemistry p. 905 - 912 (2011)

Update date:2022-07-29

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Authors:

Yuan, Mingjun

Pullarkat, Sumod A.

Li, Yongxin

Leung, Pak-Hing

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Article abstract of DOI:10.1016/j.jorganchem.2010.10.029

Cyano-functionalized allylic phosphine substrates containing the ortho-metalated (R)-(1-(dimethylamino)ethyl)naphthalene as the chiral auxiliary were synthesized from bromoacetaldehyde dimethylacetal via a one-pot process. The diastereoselective hydrophos

Full text of DOI:10.1016/j.jorganchem.2010.10.029

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