Stereoselective Cyclization of 2-(Bromophenyl)- and 2-(Iodophenyl)alkynes Catalyzed by Palladium(0) Complexes

DOI: 10.1021/jo00303a017

Source and publish data:

Journal of Organic Chemistry p. 4846 - 4849 (1990)

Update date:2022-08-04

Topics: Cyclization Stereoselective Palladium(0) Complexes

Authors:

Wang, Ren-Tzong

Chou, Fan-Lan

Luo, Fen-Tair

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Article abstract of DOI:10.1021/jo00303a017

The Pd(II)-intermediate generated by intramolecular arylation of alkynes can be further cross-coupled with phenylzinc chloride to recycle the Pd(0) catalyst and give stereodefined exocyclic indans and tetralins.For example, (Z)-1-benzylideneindan can be o

Full text of DOI:10.1021/jo00303a017

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